The Problem
Ugly effloresence stain under joint. This stain indicates that water was first absorbed by the masonry. It was drying from the visible surface and that it contained a significant amount of dissolved salts that were left behind when the water evaporated.
The Causes
Where did the water come from? It came from driving rain running down the window panes and along the sill. Water then leaks into the wall through the joint in the sill, wetting the masonry, including the mortar. Water, the universal solvent, dissolved various salts from the mortar and the masonry. During favourable weather conditions the wall dried out through the exterior surface, wicking interior moisture saturated with soluble salts from the mortar and some from the brick.